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Pseudotetrahedral cobalt(II) complexes with PNP-ligands showing uniaxial magnetic anisotropy

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Abstract

Two mononuclear pseudotetrahedral cobalt(II) complexes with the formula Co(PNP)X2, where X = Cl (1) or X = SCN (2) and PNP = bis(2-(diphenylphosphaneyl)-4-methylphenyl)amine, have been synthesised. Magnetic and high-frequency/field electron paramagnetic resonance (HF-EPR) spectroscopy and ab initio calculation studies reveal that both complexes show uniaxial magnetic anisotropy.

Graphical abstract: Pseudotetrahedral cobalt(ii) complexes with PNP-ligands showing uniaxial magnetic anisotropy

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Publication details

The article was received on 27 Apr 2018, accepted on 05 Jun 2018 and first published on 06 Jun 2018


Article type: Communication
DOI: 10.1039/C8DT01683F
Citation: Dalton Trans., 2018, Advance Article
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    Pseudotetrahedral cobalt(II) complexes with PNP-ligands showing uniaxial magnetic anisotropy

    Y. Zhai, Y. Deng and Y. Zheng, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT01683F

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