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Solvent-induced ion separation of a beryllium scorpionate complex

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Abstract

Spontaneous ion separation of the scorpionate beryllium complex, TpBeI 1 (Tp = 1-trispyrazolylborate), occurs upon treatment with THF, yielding [TpBe(thf)]I 2, which was characterized by heteronuclear NMR spectroscopy (1H, 9Be, 13C) and structurally characterized by single crystal X-ray diffraction. 2 represents a rare example of a structurally characterized monocationic beryllium complex, and to the best of our knowledge, the synthesis of 2 by a solvent-induced ion separation has previously only been observed in the reactions of beryllium dihalides with strong Lewis bases.

Graphical abstract: Solvent-induced ion separation of a beryllium scorpionate complex

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Publication details

The article was received on 24 Apr 2018, accepted on 09 May 2018 and first published on 11 May 2018


Article type: Communication
DOI: 10.1039/C8DT01640B
Citation: Dalton Trans., 2018, Advance Article
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    Solvent-induced ion separation of a beryllium scorpionate complex

    D. Naglav, B. Tobey, K. Dzialkowski, D. Bläser, C. Wölper, G. Jansen and S. Schulz, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT01640B

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