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Issue 31, 2018
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Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

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Abstract

The preparation and structural characterisation of three new heterobimetallic hydride complexes containing 3-centre,2-electron W–H–Cu bonds is reported. These complexes have been characterised by single crystal X-ray crystallography and multinuclear NMR spectroscopy. The bonding in these complexes has been analysed by DFT calculations.

Graphical abstract: Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

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Publication details

The article was received on 20 Apr 2018, accepted on 11 May 2018 and first published on 14 May 2018


Article type: Paper
DOI: 10.1039/C8DT01569D
Citation: Dalton Trans., 2018,47, 10595-10600
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    Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

    A. Hicken, A. J. P. White and M. R. Crimmin, Dalton Trans., 2018, 47, 10595
    DOI: 10.1039/C8DT01569D

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