Jump to main content
Jump to site search

Issue 24, 2018
Previous Article Next Article

Hybrid organic–inorganic connectivity of NdIII(pyrazine-N,N′-dioxide)[CoIII(CN)6]3− coordination chains for creating near-infrared emissive Nd(III) showing field-induced slow magnetic relaxation

Author affiliations

Abstract

A near-infrared emissive and magnetically anisotropic Nd(III) complex is formed within a hybrid organic–inorganic {[NdIII(pzdo)(H2O)4][CoIII(CN)6]}·0.5(pzdo)·4H2O (1) (pzdo = pyrazine-N,N′-dioxide) ladder chain built of coexisting Nd–pzdo–Nd and Nd–NC–Co molecular bridges. 1 reveals two NdIII-centered properties, a field-induced slow magnetic relaxation of a single-ion origin with a thermal energy barrier of ΔE/kB = 51(2) K at Hdc = 1 kOe, and a near-infrared fluorescence sensitized by organic and inorganic linkers.

Graphical abstract: Hybrid organic–inorganic connectivity of NdIII(pyrazine-N,N′-dioxide)[CoIII(CN)6]3− coordination chains for creating near-infrared emissive Nd(iii) showing field-induced slow magnetic relaxation

Back to tab navigation

Supplementary files

Publication details

The article was received on 13 Apr 2018, accepted on 10 May 2018 and first published on 11 May 2018


Article type: Communication
DOI: 10.1039/C8DT01464G
Citation: Dalton Trans., 2018,47, 7870-7874
  •   Request permissions

    Hybrid organic–inorganic connectivity of NdIII(pyrazine-N,N′-dioxide)[CoIII(CN)6]3− coordination chains for creating near-infrared emissive Nd(III) showing field-induced slow magnetic relaxation

    S. Chorazy, T. Charytanowicz, J. Wang, S. Ohkoshi and B. Sieklucka, Dalton Trans., 2018, 47, 7870
    DOI: 10.1039/C8DT01464G

Search articles by author

Spotlight

Advertisements