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Hybrid organic-inorganic connectivity of NdIII(pyrazine-N,N’-dioxide)[CoIII(CN)6]3- coordination chains for creating near-infrared emissive Nd(III) showing a field-induced slow magnetic relaxation

Abstract

Near-infrared emissive and magnetically anisotropic Nd(III) complex is formed within a hybrid organic-inorganic {[NdIII(pzdo) (H2O)4][CoIII(CN)6]}·0.5(pzdo)·4H2O (1) (pzdo = pyrazine -N,N’-dioxide) ladder chain built of coexisting Nd-pzdo-Nd and Nd-NC-Co molecular bridges. 1 reveals two NdIII-centered properties, a field-induced slow magnetic relaxation of a single-ion origin with thermal energy barrier of ΔE/kB = 51(2) K at Hdc = 1 kOe, and a near-infrared fluorescence sensitized by organic and inorganic linkers.

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Supplementary files

Publication details

The article was received on 13 Apr 2018, accepted on 10 May 2018 and first published on 11 May 2018


Article type: Communication
DOI: 10.1039/C8DT01464G
Citation: Dalton Trans., 2018, Accepted Manuscript
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    Hybrid organic-inorganic connectivity of NdIII(pyrazine-N,N’-dioxide)[CoIII(CN)6]3- coordination chains for creating near-infrared emissive Nd(III) showing a field-induced slow magnetic relaxation

    S. Chorazy, T. Charytanowicz, J. Wang, S. Ohkoshi and B. Sieklucka, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C8DT01464G

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