Issue 22, 2018
From the journal:

Dalton Transactions

A synthetic NO reduction cycle on a bis(pyrazolato)-bridged dinuclear ruthenium complex including photo-induced transformation†

Yasuhiro Arikawa, ORCID logo *a   Junko Hiura,a   Chika Tsuchii,a   Mika Kodama,a   Naoki Matsumotoa  and  Keisuke Umakoshi ORCID logo a  

* Corresponding authors

a Division of Chemistry and Materials Science, Graduate School of Engineering, Nagasaki University, Bunkyo-machi 1-14, Nagasaki 852-8521, Japan
E-mail: arikawa@nagasaki-u.ac.jp

Abstract

A synthetic NO reduction cycle (2NO + 2H+ + 2e− → N2O + H2O) on a dinuclear platform {(TpRu)2(μ-pz)2} (Tp = HB(pyrazol-1-yl)3) was achieved, where an unusual N–N coupling complex was included. Moreover, an interesting photo-induced conversion of the N–N coupling complex to an oxido-bridged complex was revealed.

Graphical abstract: A synthetic NO reduction cycle on a bis(pyrazolato)-bridged dinuclear ruthenium complex including photo-induced transformation

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Article information

DOI
https://doi.org/10.1039/C8DT01208C
Article type
Communication
Submitted
28 Mar 2018
Accepted
27 Apr 2018
First published
02 May 2018

Dalton Trans., 2018,47, 7399-7401

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A synthetic NO reduction cycle on a bis(pyrazolato)-bridged dinuclear ruthenium complex including photo-induced transformation

Y. Arikawa, J. Hiura, C. Tsuchii, M. Kodama, N. Matsumoto and K. Umakoshi, Dalton Trans., 2018, 47, 7399 DOI: 10.1039/C8DT01208C

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