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Selective formation of formamidines, carbodiimides and formimidates from isocyanide complexes of Mn(I) mediated by Ag2O

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Abstract

The isocyanide ligands in complexes fac-[Mn(CNR)(bipy)(CO)3]+ are selectively transformed into formamidines, carbodiimides and formimidates upon nucleophilic addition of NH2Me or alkoxides and subsequent treatment with Ag2O, which promotes tautomerization or oxidation processes of the former carbene ligands.

Graphical abstract: Selective formation of formamidines, carbodiimides and formimidates from isocyanide complexes of Mn(i) mediated by Ag2O

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Publication details

The article was received on 28 Mar 2018, accepted on 04 Apr 2018 and first published on 09 Apr 2018


Article type: Communication
DOI: 10.1039/C8DT01200H
Citation: Dalton Trans., 2018, Advance Article
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    Selective formation of formamidines, carbodiimides and formimidates from isocyanide complexes of Mn(I) mediated by Ag2O

    J. Ruiz, D. Sol, M. A. Mateo and M. Vivanco, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT01200H

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