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The first representatives of tetranuclear gold (I) complexes of P,N-containing cyclophanes.

Abstract

The first representatives of the tetranuclear gold (I) complexes of P,N-containing cyclophanes, containing two 1,5-diaza-3,7,-diphosphacyclooctane rings have been obtained. The complexation leads to the change of the ligands conformations so that the diazadiphosphacyclooctane fragments of the complexes adopt twist-chair conformations and two of four gold (I) ions are located over and under the partially collapsed macrocyclic cavity. The complexes demonstrate moderate solid-state green emission.

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Publication details

The article was received on 20 Mar 2018, accepted on 09 May 2018 and first published on 11 May 2018


Article type: Paper
DOI: 10.1039/C8DT01073K
Citation: Dalton Trans., 2018, Accepted Manuscript
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    The first representatives of tetranuclear gold (I) complexes of P,N-containing cyclophanes.

    Y. A. Nikolaeva, A. Balueva, A. A. Khafizov, I. D. Strelnik, T. Gerasimova, S. Katsyuba, I. Litvinov, E. I. Musina, A. A. Karasik and O. G. Sinyashin, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C8DT01073K

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