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Towards deriving Ni-rich cathode and oxides-based anode materials from hydroxides by sharing a facile co-precipitation method

Abstract

Although intensive studies have been conducted on the layered transition metal oxides(TMO)-based cathode materials and metal oxides-based anode materials for Li-ion batteries, their precursors generally follow different or even complex synthesis routes. To share one route for preparing precursors of the cathode and anode materials, herein, we demonstrate a facile co-precipitation method to fabricate Ni-rich hydroxide precursors of Ni0.8Co0.1Mn0.1(OH)2. Ni-rich layered oxide of LiNi0.8Co0.1Mn0.1O2 is obtained by lithiation of the precursor in air. NiO-based anode material is prepared by calcining the precursor or multi-walled carbon nanotubes (MWCNTs) incorporated precursors. The pre-addition of ammonia solution can simplify the co-precipitation procedures and the use of air atmosphere can also make heat treatment facile. LiNi0.8Co0.1Mn0.1O2 as cathode material delivers a reversible capacity of 194 mAh g−1 at 40 mA g−1 and notable cycling retention of 88.8% after 100 cycles at 200 mA g−1. This noticeable performance of the cathode arises from decent particle morphology and high crystallinity of the layered oxides. As anode material, the MWCNTs-incorporated oxides deliver a much higher reversible capacity of 811.1 mAh g−1 after 200 cycles compared to the pristine oxides without MWCNTs. The improvement on electrochemical performance can be attributed to synergistic effects from MWCNTs incorporation, including reinforced electronic conductivity, rich meso-pores and alleviated volume effect. This facile and sharing method may offer an integrated and economic approach for commercial production of Ni-rich electrode materials for Li-ion batteries.

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Supplementary files

Publication details

The article was received on 08 Mar 2018, accepted on 13 Apr 2018 and first published on 16 Apr 2018


Article type: Paper
DOI: 10.1039/C8DT00893K
Citation: Dalton Trans., 2018, Accepted Manuscript
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    Towards deriving Ni-rich cathode and oxides-based anode materials from hydroxides by sharing a facile co-precipitation method

    H. Qiu, T. Du, J. Wu, Y. Wang, J. Liu, S. Ye and S. Liu, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C8DT00893K

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