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Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates

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Abstract

Utilization of [Mo2S2O2(H2O)6]2+ and a tellurite anion led to the formation of three new clusters, 1–3, with unique structural features. The tellurite anion not only templated the formation of [(Mo2O2S2)4(TeO3)(OH)9]3− 1 and [(Mo2O2S2)12(TeO3)4(TeO4)2 (OH)18]10− 3, but also the in situ generation of two different types of dimeric {Te2O6} based moieties induced the spontaneous assembly of the chiral [(Mo2O2S2)10(TeO3)(Te2O6)2(OH)18]8− anionic cluster, 2.

Graphical abstract: Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates

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Publication details

The article was received on 04 Mar 2018, accepted on 28 Mar 2018 and first published on 29 Mar 2018


Article type: Communication
DOI: 10.1039/C8DT00832A
Citation: Dalton Trans., 2018, Advance Article
  • Open access: Creative Commons BY license
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    Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates

    J. W. Purcell, D. Long, E. C. Lee, L. Cronin and H. N. Miras, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT00832A

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