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Unique and contrasting structures of homoleptic lanthanum(III) and cerium(III) 3,5-dimethylpyrazolates

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Abstract

Homoleptic [La(Me2pz)3]n (Me2pz = 3,5-dimethylpyrazolato) is a μ–η25-Me2pz coordination polymer with 12-coordinate La atoms in an unusual η55 Me2pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce4(Me2pz)12] featuring six different Me2pz coordination modes.

Graphical abstract: Unique and contrasting structures of homoleptic lanthanum(iii) and cerium(iii) 3,5-dimethylpyrazolates

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Publication details

The article was received on 25 Jan 2018, accepted on 04 Apr 2018 and first published on 09 Apr 2018


Article type: Communication
DOI: 10.1039/C8DT00338F
Citation: Dalton Trans., 2018, Advance Article
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    Unique and contrasting structures of homoleptic lanthanum(III) and cerium(III) 3,5-dimethylpyrazolates

    D. Werner, U. Bayer, N. E. Rad, P. C. Junk, G. B. Deacon and R. Anwander, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT00338F

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