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Issue 12, 2018
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Nonanuclear Ni(II) complexes in a [1-7-1] formation derived from asymmetric multidentate ligands: magnetic and electrochemical properties

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Abstract

Nonanuclear Ni(II) complexes, [Ni9(Ln)6(OH)6(H2O)6] (Ni9Ln, n = 1–4; H2Ln = 6-acetoacetyl-2-pyridinecarboxylic acid derivatives), were prepared via self-assembly using the asymmetric multidentate ligands H2Ln. A corner-sharing tetrahedron-type structure, [Ni73-OH)6]8+, and terminal mononuclear units constitute the nonanuclear structure in a [1-7-1] formation. The electrochemical and magnetic properties of Ni9Ln were modulated by the introduction of various substituents in H2Ln.

Graphical abstract: Nonanuclear Ni(ii) complexes in a [1-7-1] formation derived from asymmetric multidentate ligands: magnetic and electrochemical properties

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Publication details

The article was received on 12 Jan 2018, accepted on 29 Jan 2018 and first published on 29 Jan 2018


Article type: Communication
DOI: 10.1039/C8DT00161H
Citation: Dalton Trans., 2018,47, 4036-4039
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    Nonanuclear Ni(II) complexes in a [1-7-1] formation derived from asymmetric multidentate ligands: magnetic and electrochemical properties

    Y. Tsuji, T. Togo, A. Mishima, T. Koshiyama and M. Ohba, Dalton Trans., 2018, 47, 4036
    DOI: 10.1039/C8DT00161H

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