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A nitrogen-rich ligand as a scaffold for slow magnetic relaxation in dysprosium-based 0D and 1D architectures

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Abstract

A recently designed nitrogen-rich ligand is successfully applied as a scaffold for lanthanide ions to show that the intricate chemistry of energetic materials can be combined with other fields of research, including that of molecular magnetism. Herein, we report the synthesis of two different types of molecular architectures using a single ligand template, in which the discrete monomer exhibits single-molecule magnet-like behaviour along with two well-isolated modes of magnetic relaxation.

Graphical abstract: A nitrogen-rich ligand as a scaffold for slow magnetic relaxation in dysprosium-based 0D and 1D architectures

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Publication details

The article was received on 12 Jan 2018, accepted on 08 Feb 2018 and first published on 08 Feb 2018


Article type: Paper
DOI: 10.1039/C8DT00146D
Citation: Dalton Trans., 2018, Advance Article
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    A nitrogen-rich ligand as a scaffold for slow magnetic relaxation in dysprosium-based 0D and 1D architectures

    G. Brunet, E. Sebastiao, T. G. Witkowski, I. Korobkov, B. Gabidullin and M. Murugesu, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT00146D

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