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Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate

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Abstract

A monomeric trinickel(II)-substituted phosphotungstate [H9P2W15O62Ni3]9− ion is stabilized by grafting three {Re(CO)3} organometallic groups on the surface for the first time. Magnetic measurements manifest that the resulting complex, Na(NH4)5[P2W15O56Ni3(H2O)33-OH)3(Re(CO)3)3]·18H2O (1), displays overall ferromagnetic interactions with the presence of ZFS for Ni2+ at low temperature.

Graphical abstract: Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate

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Publication details

The article was received on 11 Jan 2018, accepted on 02 Apr 2018 and first published on 02 Apr 2018


Article type: Communication
DOI: 10.1039/C8DT00138C
Citation: Dalton Trans., 2018, Advance Article
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    Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate

    J. Jia, P. Ma, P. Zhang, D. Zhang, C. Zhang, J. Niu and J. Wang, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT00138C

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