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Buchwald-Hartwig Amination Using Pd(I) Dimer Precatalysts Supported by Biaryl Phosphine Ligands

Abstract

We report the synthesis of air-stable Pd(I) dimer complexes featuring biaryl phosphine ligands. Catalytic experiments suggest that these complexes are comptent precatalysts that can mediate cross-coupling amination reactions between aryl halides with both aliphatic and aromatic amine nucleophiles. This work represents an expansion of the air-stable precatalyst toolbox for Pd-catalyzed cross-coupling transformations.

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Publication details

The article was received on 10 Jan 2018, accepted on 09 Feb 2018 and first published on 12 Feb 2018


Article type: Communication
DOI: 10.1039/C8DT00119G
Citation: Dalton Trans., 2018, Accepted Manuscript
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    Buchwald-Hartwig Amination Using Pd(I) Dimer Precatalysts Supported by Biaryl Phosphine Ligands

    A. Spokoyny, K. Kirlikovali, E. Cho, T. J. Downard, L. Grigoryan, Z. Han, S. Hong, D. Jung, J. C. Quintana, V. Reynoso, S. Ro, Y. Shen, K. Swartz, E. Ter Sahakyan, A. I. Wixtrom, B. Yoshida and A. L. Rheingold, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C8DT00119G

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