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Issue 13, 2018
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Through-conjugation of two phosphaalkyne (‘C[triple bond, length as m-dash]P’) moieties mediated by a bimetallic scaffold

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Abstract

Through-conjugation of two phosphaalkyne moieties within an isolable molecule is demonstrated for the first time with the synthesis of [{Ru(dppe)2}2{μ-(C[triple bond, length as m-dash]C)2C6H4-p}(C[triple bond, length as m-dash]P)2], via base-induced desilylation of [{Ru(dppe)2}2{μ-(C[triple bond, length as m-dash]C)2C6H4-p}(η1-P[triple bond, length as m-dash]CSiMe3)2]2+. The nature of the cyaphide ligands and their influence upon the bimetallic core are studied electrochemically.

Graphical abstract: Through-conjugation of two phosphaalkyne (‘C [[triple bond, length as m-dash]] P’) moieties mediated by a bimetallic scaffold

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Publication details

The article was received on 10 Jan 2018, accepted on 06 Feb 2018 and first published on 28 Feb 2018


Article type: Communication
DOI: 10.1039/C8DT00110C
Citation: Dalton Trans., 2018,47, 4428-4432
  • Open access: Creative Commons BY license
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    Through-conjugation of two phosphaalkyne (‘C[triple bond, length as m-dash]P’) moieties mediated by a bimetallic scaffold

    Matthew. C. Leech and I. R. Crossley, Dalton Trans., 2018, 47, 4428
    DOI: 10.1039/C8DT00110C

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