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Sulfur-Containing Bimetallic Metal Organic Frameworks with Multi-Fold Helix as Anode of Lithium Ion Batteries

Abstract

We utilise the dual synthesis strategy in terms of bimetallic inorganic building blocks and sulfur containing organic ligand, a novel sulfur-containing bimetallic metal organic framework (Fe2Co-TPDC) with two types of 4-fold meso-helical structure has been successfully synthesized. Benefitting from the uniform distribution of active sulfur sites and the structural stability of mixed-metallic method, Fe2Co-TPDC can efficiently prevent a shuttle behavior of sulfur and endow a commendable specific capacity. And for all we know, this is the first time that the sulfur-containing bimetallic crystalline MOF with helical structure served as a electrode material for LIBs with prominent specific capacity and remarkable cycling stability.

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Publication details

The article was received on 09 Jan 2018, accepted on 30 Jan 2018 and first published on 30 Jan 2018


Article type: Paper
DOI: 10.1039/C8DT00095F
Citation: Dalton Trans., 2018, Accepted Manuscript
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    Sulfur-Containing Bimetallic Metal Organic Frameworks with Multi-Fold Helix as Anode of Lithium Ion Batteries

    M. Li, N. Kong, Y. Lan and Z. Su, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C8DT00095F

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