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Issue 16, 2018
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A thermoelectric copper-iodide composite from the pyrolysis of a well-defined coordination polymer

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Abstract

Coordination polymer 1 was prepared from CuI and a flexible [SNS] ligand L in acetonitrile. The thermal decomposition of 1 yielded a CuI-rich thermoelectric carbon composite 2, which is relatively light, thermally stable and robust. Composite 2 possesses high Seebeck coefficients (700–950 μV K−1) from rt to 204 °C after an optimization cycle.

Graphical abstract: A thermoelectric copper-iodide composite from the pyrolysis of a well-defined coordination polymer

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Publication details

The article was received on 09 Jan 2018, accepted on 15 Mar 2018 and first published on 16 Mar 2018


Article type: Communication
DOI: 10.1039/C8DT00090E
Citation: Dalton Trans., 2018,47, 5564-5569
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    A thermoelectric copper-iodide composite from the pyrolysis of a well-defined coordination polymer

    S. Bai, I. H. K. Wong, M. Lin, D. J. Young and T. S. A. Hor, Dalton Trans., 2018, 47, 5564
    DOI: 10.1039/C8DT00090E

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