Jump to main content
Jump to site search


A novel 3-D cuprous iodide polymer with a high Cu/I ratio

Author affiliations

Abstract

A novel 3-D cuprous iodide polymer [CuI3I(μ6-L)]n with a Cu/I ratio as high as 3 (1, H2L = 1,3-bis(2H-tetrazol-5-yl)benzene) has been hydrothermally synthesized. The 3-D framework of 1 is constructed by the linkages of rare 1-D cationic aggregates [CuI3I2+]n and anionic bi-tetrazolate bridges. 1 shows unusually thermochromic luminescent and photocatalytic properties, and its density functional theory calculation has also been studied.

Graphical abstract: A novel 3-D cuprous iodide polymer with a high Cu/I ratio

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 Jan 2018, accepted on 03 Feb 2018 and first published on 05 Feb 2018


Article type: Communication
DOI: 10.1039/C8DT00054A
Citation: Dalton Trans., 2018, Advance Article
  •   Request permissions

    A novel 3-D cuprous iodide polymer with a high Cu/I ratio

    H. Xiao, J. Zhou, X. Liu, H. Xiao, R. A. S. Ferreira, L. D. Carlos and L. Fu, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT00054A

Search articles by author

Spotlight

Advertisements