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A homoleptic chromium(III) carboxylate

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Structurally characterized chromium(III) carboxylates form clusters with a variety of bridging groups introduced from aqueous reaction conditions. The first homoleptic monomeric chromium(III) carboxylate has been prepared using an anhydrous salt metathesis synthetic route. The carboxylate groups coordinate the chromium in a bidentate chelate yielding an aliphatic soluble complex. The complex was characterized by a variety of methods including high energy X-ray diffraction, FD-MS, IR and Raman spectroscopy, complemented by DFT modeling.

Graphical abstract: A homoleptic chromium(iii) carboxylate

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The article was received on 03 Jan 2018, accepted on 07 Mar 2018 and first published on 14 Mar 2018

Article type: Communication
DOI: 10.1039/C8DT00029H
Citation: Dalton Trans., 2018, Advance Article
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    A homoleptic chromium(III) carboxylate

    O. L. Sydora, R. T. Hart, N. A. Eckert, E. Martinez Baez, A. E. Clark and C. J. Benmore, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT00029H

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