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Issue 14, 2018
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A homoleptic chromium(III) carboxylate

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Abstract

Structurally characterized chromium(III) carboxylates form clusters with a variety of bridging groups introduced from aqueous reaction conditions. The first homoleptic monomeric chromium(III) carboxylate has been prepared using an anhydrous salt metathesis synthetic route. The carboxylate groups coordinate the chromium in a bidentate chelate yielding an aliphatic soluble complex. The complex was characterized by a variety of methods including high energy X-ray diffraction, FD-MS, IR and Raman spectroscopy, complemented by DFT modeling.

Graphical abstract: A homoleptic chromium(iii) carboxylate

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Publication details

The article was received on 03 Jan 2018, accepted on 07 Mar 2018 and first published on 14 Mar 2018


Article type: Communication
DOI: 10.1039/C8DT00029H
Citation: Dalton Trans., 2018,47, 4790-4793
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    A homoleptic chromium(III) carboxylate

    O. L. Sydora, R. T. Hart, N. A. Eckert, E. Martinez Baez, A. E. Clark and C. J. Benmore, Dalton Trans., 2018, 47, 4790
    DOI: 10.1039/C8DT00029H

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