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Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds

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Abstract

A low-coordinate iron(II) complex (CztBu(PztBu)2)Fe[N(SiMe3)2], 1 bearing an NNN-pincer ligand was prepared and fully characterized. Intramolecular C–H activation on the 5-position of a pyrazole at elevated temperatures was observed. Complex 1 was found to be an efficient and chemoselective pre-catalyst for the hydrosilylation of organo carbonyl substrates.

Graphical abstract: Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds

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Publication details

The article was received on 03 Jan 2018, accepted on 26 Jan 2018 and first published on 26 Jan 2018


Article type: Communication
DOI: 10.1039/C7DT04928E
Citation: Dalton Trans., 2018, Advance Article
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    Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds

    H. Lin, S. Lutz, C. O'Kane, M. Zeller, C. Chen, T. Al Assil and W. Lee, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C7DT04928E

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