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A novel trigonal propeller-shaped hybrid tri-Neodymium-polyoxometalate exhibiting single-molecule magnet behavior

Abstract

A trigonal propeller-shaped hybrid polyoxometalate (POM) (NH2Me2)3{[Nd(Mo4O13)(DMF)4]3(BTC)2}∙8DMF (1; BTC = 1,3,5-benzenetricarboxylate) has been synthesized and structurally characterized. The planar {Mo4} segment is tailored from the precursor Lindqvist polyoxoanion [Mo6O19]2- firstly, and plays a key role in the reassembly of 1. Furthermore, the magnetic studies reveal that 1 shows single-molecule magnet (SMM) behavior.

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Publication details

The article was accepted on 08 Jan 2018 and first published on 08 Jan 2018


Article type: Communication
DOI: 10.1039/C7DT04908K
Citation: Dalton Trans., 2018, Accepted Manuscript
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    A novel trigonal propeller-shaped hybrid tri-Neodymium-polyoxometalate exhibiting single-molecule magnet behavior

    H. Zhang, X. Wu, J. Liao, X. Kuang, W. Yang and C. Lu, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C7DT04908K

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