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Issue 6, 2018
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A novel trigonal propeller-shaped hybrid tri-neodymium-polyoxometalate exhibiting single-molecule magnet behavior

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Abstract

A trigonal propeller-shaped hybrid polyoxometalate (POM) (NH2Me2)3{[Nd(Mo4O13)(DMF)4]3(BTC)2}·8DMF (1; BTC = 1,3,5-benzenetricarboxylate) has been synthesized and structurally characterized. The planar {Mo4} segment is tailored from the precursor Lindqvist polyoxoanion [Mo6O19]2− firstly, and plays a key role in the reassembly of 1. Furthermore, the magnetic studies reveal that 1 shows single-molecule magnet (SMM) behavior.

Graphical abstract: A novel trigonal propeller-shaped hybrid tri-neodymium-polyoxometalate exhibiting single-molecule magnet behavior

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Publication details

The article was received on 28 Dec 2017, accepted on 08 Jan 2018 and first published on 08 Jan 2018


Article type: Communication
DOI: 10.1039/C7DT04908K
Citation: Dalton Trans., 2018,47, 1796-1800
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    A novel trigonal propeller-shaped hybrid tri-neodymium-polyoxometalate exhibiting single-molecule magnet behavior

    H. Zhang, X. Wu, J. Liao, X. Kuang, W. Yang and C. Lu, Dalton Trans., 2018, 47, 1796
    DOI: 10.1039/C7DT04908K

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