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Issue 10, 2018
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A 3D neutral chalcogenide framework built from a supertetrahedral T3 cluster and a metal complex for the electrocatalytic oxygen reduction reaction

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Abstract

Herein we report a new 3D neutral chalcogenide framework constructed by using a supertetrahedral T3 cluster ([Mn2Ga4Sn4S20]) as the building unit and a metal complex ([Mn(dach)2], dach = 1,2-diaminocyclohexane) as the linker. Significantly, the obtained material exhibits high-efficiency electrocatalytic oxygen reduction activity with quasi-four-electron transfer and a small Tafel slope, much better than that of commercial Pt/C (10 wt%).

Graphical abstract: A 3D neutral chalcogenide framework built from a supertetrahedral T3 cluster and a metal complex for the electrocatalytic oxygen reduction reaction

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Publication details

The article was received on 27 Dec 2017, accepted on 31 Jan 2018 and first published on 31 Jan 2018


Article type: Communication
DOI: 10.1039/C7DT04891B
Citation: Dalton Trans., 2018,47, 3227-3230
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    A 3D neutral chalcogenide framework built from a supertetrahedral T3 cluster and a metal complex for the electrocatalytic oxygen reduction reaction

    Y. Zhang, D. Hu, C. Xue, H. Yang, X. Wang and T. Wu, Dalton Trans., 2018, 47, 3227
    DOI: 10.1039/C7DT04891B

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