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Issue 8, 2018
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N,N-Disubstituted-N′-acylthioureas as modular ligands for deposition of transition metal sulfides

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Abstract

First row transition metal complexes (Ni, Co, Cu, Zn) with N,N-disubstituted-N′-acylthiourea ligands have been synthesized and characterized. Bis(N,N-diisopropyl-N′-cinnamoylthiourea)nickel was found to have the lowest onset temperature for thermal decomposition. Thin film deposition of Ni, Co, and Zn sulfides by aerosol assisted chemical vapor deposition from their respective N,N-diisopropyl-N′-cinnamoylthiourea complexes at 350 °C has been demonstrated.

Graphical abstract: N,N-Disubstituted-N′-acylthioureas as modular ligands for deposition of transition metal sulfides

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Publication details

The article was received on 22 Dec 2017, accepted on 28 Jan 2018 and first published on 29 Jan 2018


Article type: Paper
DOI: 10.1039/C7DT04860B
Citation: Dalton Trans., 2018,47, 2719-2726
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    N,N-Disubstituted-N′-acylthioureas as modular ligands for deposition of transition metal sulfides

    Z. Ali, N. E. Richey, D. C. Bock, K. A. Abboud, J. Akhtar, M. Sher and L. McElwee-White, Dalton Trans., 2018, 47, 2719
    DOI: 10.1039/C7DT04860B

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