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Issue 6, 2018
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Homoleptic U(III) and U(IV) amidate complexes

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Abstract

The syntheses of the first homoleptic U(III) and U(IV) amidate complexes are described. These can be interconverted by chemical reduction/oxidation, showing an unusual change in coordination number from four in the U(III) complex to eight in the U(IV) complex in the solid state structures.

Graphical abstract: Homoleptic U(iii) and U(iv) amidate complexes

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Publication details

The article was received on 21 Dec 2017, accepted on 10 Jan 2018 and first published on 18 Jan 2018


Article type: Communication
DOI: 10.1039/C7DT04813K
Citation: Dalton Trans., 2018,47, 1772-1776
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    Homoleptic U(III) and U(IV) amidate complexes

    M. D. Straub, S. Hohloch, S. G. Minasian and J. Arnold, Dalton Trans., 2018, 47, 1772
    DOI: 10.1039/C7DT04813K

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