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Bromine-rich complexes of bismuth: experimental and theoretical studies

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Abstract

Three novel polybromide complexes of bismuth(III) – (2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3) – were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(III) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(III) polybromides was investigated by theoretical methods, enabling the estimation of their energies.

Graphical abstract: Bromine-rich complexes of bismuth: experimental and theoretical studies

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Publication details

The article was received on 19 Dec 2017, accepted on 21 Jan 2018 and first published on 22 Jan 2018


Article type: Paper
DOI: 10.1039/C7DT04779G
Citation: Dalton Trans., 2018, Advance Article
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    Bromine-rich complexes of bismuth: experimental and theoretical studies

    S. A. Adonin, I. D. Gorokh, A. S. Novikov, D. G. Samsonenko, P. E. Plyusnin, M. N. Sokolov and V. P. Fedin, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C7DT04779G

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