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A stable thiolato–CuI–thiolato triple linkage that bridges two cobalt(III) centres

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Abstract

Treatment of Λ-fac-[Co(D-pen-N,S)3]3– (D-H2pen = D-penicillamine) with Cu+ in water gave a stable CoIII2CuI3 complex, ΛΛ-[Co2Cu3(D-pen)6]3– ([1]3–), having three thiolato–copper(I)–thiolato moieties that bridge two cobalt(III) centres. Complex [1]3– was isolated as a coordination polymer of Na3[1], which was converted to a complex salt of [Cr(H2O)6][1] by treatment with Cr(NO3)3.

Graphical abstract: A stable thiolato–CuI–thiolato triple linkage that bridges two cobalt(iii) centres

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Publication details

The article was received on 18 Dec 2017, accepted on 12 Jan 2018 and first published on 29 Jan 2018


Article type: Communication
DOI: 10.1039/C7DT04760F
Citation: Dalton Trans., 2018, Advance Article
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    A stable thiolato–CuI–thiolato triple linkage that bridges two cobalt(III) centres

    N. Oya, M. Yamada, S. Surinwong, N. Kuwamura and T. Konno, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C7DT04760F

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