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Slow magnetic relaxation influenced by symmetry change from ideal Ci to D3d in cobalt(II)-based single-ion magnets

Abstract

The coordination geometries of the Co(II) site in two complexes [Co(imidazole)6][BPh4]2∙0.3CH3CN (1) and [Co(imidazole)6][NO3]2 (2) display the ideal symmetries Ci and D3d, respectively. Both complexes are field-induced single-ion magnets. The effective energy barrier exhibits a reduced tendency with the local symmetries changing from low-symmetry Ci to high-symmetry D3d.

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Publication details

The article was received on 08 Dec 2017, accepted on 09 Jan 2018 and first published on 09 Jan 2018


Article type: Communication
DOI: 10.1039/C7DT04651K
Citation: Dalton Trans., 2018, Accepted Manuscript
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    Slow magnetic relaxation influenced by symmetry change from ideal Ci to D3d in cobalt(II)-based single-ion magnets

    L. Chen, J. Zhou, H. Cui, A. Yuan, Z. Wang, Y. Zhang, Z. Ouyang and Y. Song, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C7DT04651K

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