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Issue 7, 2018
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Could new U(II) complexes be accessible via tuning hybrid heterocalix[4]arene? A theoretical study of redox and structural properties

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Abstract

Tuning the building blocks of pyrrole and arene/pyridine in hybrid heterocalix[4]arene allows for the possible accessibility of several intriguing divalent uranium complexes, which are energetically stabilized by enhanced δ(U–Ar) bonds and further corroborated by computed UIII/II reduction potentials.

Graphical abstract: Could new U(ii) complexes be accessible via tuning hybrid heterocalix[4]arene? A theoretical study of redox and structural properties

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Publication details

The article was received on 04 Dec 2017, accepted on 08 Jan 2018 and first published on 09 Jan 2018


Article type: Communication
DOI: 10.1039/C7DT04557C
Citation: Dalton Trans., 2018,47, 2148-2151
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    Could new U(II) complexes be accessible via tuning hybrid heterocalix[4]arene? A theoretical study of redox and structural properties

    H. Zhao, M. Zheng, G. Schreckenbach and Q. Pan, Dalton Trans., 2018, 47, 2148
    DOI: 10.1039/C7DT04557C

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