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Title Could new U(II) complexes be accessible via tuning hybrid heterocalix[4]arene? A theoretical study of redox and structural properties

Abstract

Tuning building blocks of pyrrole and arene/pyridine in hybrid heterocalix[4]arene allows for possible accessibility of several intriguing divalent uranium complexes, which are energetically stabilized by enhanced δ(U-Ar) bonds and further corroborated by computed UIII/II reduction potentials.

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Publication details

The article was received on 04 Dec 2017, accepted on 08 Jan 2018 and first published on 09 Jan 2018


Article type: Communication
DOI: 10.1039/C7DT04557C
Citation: Dalton Trans., 2018, Accepted Manuscript
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    Title Could new U(II) complexes be accessible via tuning hybrid heterocalix[4]arene? A theoretical study of redox and structural properties

    H. Zhao, M. Zheng, H. G. Schreckenbach and Q. Pan, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C7DT04557C

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