Jump to main content
Jump to site search

Issue 5, 2018
Previous Article Next Article

Self-assembled energetic 3D metal–organic framework [Na8(N5)8(H2O)3]n based on cyclo-N5

Author affiliations

Abstract

From a 1D sodium-N5 framework, a new zeolite-like metal–organic framework (MOF) with a fascinating 3D structure was successfully constructed. It exhibited an enhanced thermal stability with a decomposition temperature (onset) of 129 °C and an enhanced coordination ability (five-coordination) of cyclo-N5 in weak alkaline conditions. The 3D MOF with a bulky size offers new opportunities not only for the formation of porous materials but also to control the balance between the performance and stability of polynitrogen materials.

Graphical abstract: Self-assembled energetic 3D metal–organic framework [Na8(N5)8(H2O)3]n based on cyclo-N5–

Back to tab navigation

Supplementary files

Publication details

The article was received on 29 Nov 2017, accepted on 29 Dec 2017 and first published on 29 Dec 2017


Article type: Communication
DOI: 10.1039/C7DT04501H
Citation: Dalton Trans., 2018,47, 1398-1401
  •   Request permissions

    Self-assembled energetic 3D metal–organic framework [Na8(N5)8(H2O)3]n based on cyclo-N5

    Y. Xu, P. Wang, Q. Lin, X. Mei and M. Lu, Dalton Trans., 2018, 47, 1398
    DOI: 10.1039/C7DT04501H

Search articles by author

Spotlight

Advertisements