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Challenge in Optoelectronic Duple Switches: A Red Emission Large-size Single Crystal and Unidirectional Flexible Thin Film in a Hybrid Multifunctional Material

Abstract

Photoelectric dual-function features in bulk crystals or flexible thin films presents a class of important and thriving applications in storage, sensing and other information fields. Based on superiority advantages, such as easy and environmentally friendly processing, mechanical flexibility, fabrication of films, and the bulk single crystal, we designed a kind of molecular material with a photoelectric multi-function switch, [N(NH2CH2CH2)3]2Mn2Cl12 (compound 1), which exhibits an intriguing temperature-dependent dielectric and red emission switchable characteristics. This material perfectly explains the advantages of molecular materials while 1 can also get transparent unidirectional film with ultra-flexible characteristic. And this material shows the highest record in signal contrast of ≈5 (exceeding all the known molecular materials/crystalline switches, revealing its potential to obtain high-efficiency signal-to-noise ratio), sensitive dielectric bi-stability, and excellent switching anti fatigue, those features give it a high application value in integrated circuits, optoelectronic seamless integration devices and flexible multifunctional devices.

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Publication details

The article was received on 29 Nov 2017, accepted on 12 Jan 2018 and first published on 12 Jan 2018


Article type: Paper
DOI: 10.1039/C7DT04489E
Citation: Dalton Trans., 2018, Accepted Manuscript
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    Challenge in Optoelectronic Duple Switches: A Red Emission Large-size Single Crystal and Unidirectional Flexible Thin Film in a Hybrid Multifunctional Material

    X. Zhu, W. Zhang, C. Chen, Q. Ye and D. Fu, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C7DT04489E

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