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Supramolecular self-assembly of heterobimetallic complexes: a new N,P-based, selective heteroditopic ligand

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Abstract

Pyrimidine-hydrazone and phosphole architectures have been combined to create a new heteroditopic ligand capable of forming heterobimetallic ZnII/PdII, PbII/PdII and CuII/PdII complexes in high yielding stepwise or one pot reactions. The catalytic activity of these complexes in Heck coupling and Miyaura borylation reactions was investigated.

Graphical abstract: Supramolecular self-assembly of heterobimetallic complexes: a new N,P-based, selective heteroditopic ligand

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Publication details

The article was received on 26 Nov 2017, accepted on 11 Dec 2017 and first published on 12 Dec 2017


Article type: Paper
DOI: 10.1039/C7DT04449F
Citation: Dalton Trans., 2018, Advance Article
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    Supramolecular self-assembly of heterobimetallic complexes: a new N,P-based, selective heteroditopic ligand

    D. J. Hutchinson, R. Clauss, M. Sárosi and E. Hey-Hawkins, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C7DT04449F

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