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Neutral two-dimensional organometallic–organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

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Abstract

The reaction of the Pn ligand complex [Cp*Fe(η5-P5)] (1: Cp* = η5-C5Me5) with CuCl in the presence of 4,4′-bipyridine or 1,2-di(4-pyridyl)ethylene leads to the formation of three unprecedented neutral 2D organometallic–organic hybrid networks, the constitutional isomers [Cu2Cl2{Cp*Fe(μ35:1:1-P5)}(μ,η1:1-C10H8N2)]n (2 and 3) and the coordination polymer [(CuCl)2{Cp*Fe(μ35:1:1-P5)}(μ,η1:1-C12H10N2)]n (4) with isomeric square (2 and 3) and honeycomb (4) layer topologies.

Graphical abstract: Neutral two-dimensional organometallic–organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

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Publication details

The article was received on 13 Nov 2017, accepted on 08 Dec 2017 and first published on 08 Dec 2017


Article type: Communication
DOI: 10.1039/C7DT04286H
Citation: Dalton Trans., 2018, Advance Article
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    Neutral two-dimensional organometallic–organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

    M. Elsayed Moussa, B. Attenberger, E. V. Peresypkina and M. Scheer, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C7DT04286H

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