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Issue 5, 2018
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Reversible three equal-step spin crossover in an iron(II) Hofmann-type metal–organic framework

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Abstract

A novel bent ligand-pillared three-dimensional Hofmann-type metal–organic framework, [FeII(Hbpt)Pt(CN)4]·1/2Hbpt·1/2CH3OH·5/2H2O [1, Hbpt = 4,4′-(1H-1,2,4-triazole-3,5-diyl) dipyridine], was synthesized and crystallographically and magnetically characterized, which showed incomplete three-step spin-crossover behavior with a reversible three equal-step sequence of HS1.00 ↔ HS0.75LS0.25 ↔ HS0.5LS0.5 ↔ HS0.25LS0.75.

Graphical abstract: Reversible three equal-step spin crossover in an iron(ii) Hofmann-type metal–organic framework

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Publication details

The article was received on 08 Nov 2017, accepted on 22 Dec 2017 and first published on 22 Dec 2017


Article type: Communication
DOI: 10.1039/C7DT04205A
Citation: Dalton Trans., 2018,47, 1407-1411
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    Reversible three equal-step spin crossover in an iron(II) Hofmann-type metal–organic framework

    F. Liu, D. Li, L. Su and J. Tao, Dalton Trans., 2018, 47, 1407
    DOI: 10.1039/C7DT04205A

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