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Issue 3, 2018
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MnAPO-5 as an efficient heterogeneous catalyst for selective liquid phase partial oxidation reactions

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Abstract

Heterogeneous catalysts play a key role in addressing the economic and environmental issues of the chemical industry due to their several advantages, like ease of product separation, work-up and high recycling efficiency. Herein, we report the synthesis of a robust manganese(IV)-containing aluminophosphate material (MnAPO-5), with an AFI framework topology. This material has been characterized thoroughly by powder XRD, XPS, UHR TEM, FE SEM, 31P CP MAS NMR, atomic absorption spectroscopy, UV-visible spectroscopy and TGA. The Mn-containing microporous material has been employed as a heterogeneous catalyst for the oxidation of styrene and the synthesis of adipic acid from cyclohexanone in the presence of tert-butyl hydroperoxide (TBHP) as the oxidant in air and it displayed very high recycling efficiency.

Graphical abstract: MnAPO-5 as an efficient heterogeneous catalyst for selective liquid phase partial oxidation reactions

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Publication details

The article was received on 16 Oct 2017, accepted on 04 Dec 2017 and first published on 05 Dec 2017


Article type: Paper
DOI: 10.1039/C7DT03897F
Citation: Dalton Trans., 2018,47, 791-798
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    MnAPO-5 as an efficient heterogeneous catalyst for selective liquid phase partial oxidation reactions

    S. Chatterjee, P. Bhanja, L. Paul, M. Ali and A. Bhaumik, Dalton Trans., 2018, 47, 791
    DOI: 10.1039/C7DT03897F

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