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Li6Na3Sr14Al11P22O90: an oxo-centered Al3 cluster based phosphate constructed from two types of (3,6)-connected kgd layers

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Abstract

A novel and thermally stable aluminum phosphate Li6Na3Sr14Al11P22O90 (1) has been achieved by using a solid-state molten method, which contains an oxo-centered trinuclear cluster and an anti-Lowenstein's rule Al–O–Al linkage and is constructed from two types of (3,6)-connected kgd layers [Al(Al3O)(PO4)7]25− and [Al(PO4)2]3−. The good optical transparency in the whole UV range and excellent thermal stability make the title compound a potential optical window material.

Graphical abstract: Li6Na3Sr14Al11P22O90: an oxo-centered Al3 cluster based phosphate constructed from two types of (3,6)-connected kgd layers

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Publication details

The article was received on 13 Oct 2017, accepted on 28 Nov 2017 and first published on 28 Nov 2017


Article type: Communication
DOI: 10.1039/C7DT03854B
Citation: Dalton Trans., 2018, Advance Article
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    Li6Na3Sr14Al11P22O90: an oxo-centered Al3 cluster based phosphate constructed from two types of (3,6)-connected kgd layers

    X. Yao, Y. Chen, Y. Guo, Y. Jia, X. Jiang and X. Zhang, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C7DT03854B

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