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Issue 10, 2018
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Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(IV) complexes: aromatic versus benzylic hydroxylation of aromatic aldehydes

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Abstract

The present study describes the first example of the hydroxylation of benzaldehydes by synthetic nonheme oxoiron(IV) complexes, where the reactivity, chemoselectivity, and mechanism were strongly influenced by the ligand environment of the iron center.

Graphical abstract: Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(iv) complexes: aromatic versus benzylic hydroxylation of aromatic aldehydes

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Publication details

The article was received on 04 Oct 2017, accepted on 25 Jan 2018 and first published on 05 Feb 2018


Article type: Communication
DOI: 10.1039/C7DT03727A
Citation: Dalton Trans., 2018,47, 3248-3252
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    Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(IV) complexes: aromatic versus benzylic hydroxylation of aromatic aldehydes

    R. Turcas, D. Lakk-Bogáth, G. Speier and J. Kaizer, Dalton Trans., 2018, 47, 3248
    DOI: 10.1039/C7DT03727A

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