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Induced chirality and reversal of phosphomolybdate cluster via modulating its interaction with cyclodextrins

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Abstract

The distinctive chirality change of a polyoxometalate cluster PMo12O403−, induced by cyclodextrins (CDs), was investigated in concentrated aqueous solutions. The host–guest interactions between the used inorganic cluster and the organic CD molecules were then identified to maintain the induced chirality. The supramolecular inclusion at the primary hydroxyl side of CDs was demonstrated to be critical in modulating the formed chirality, while the induced chirality reversal was realized by simply substituting a CD with a supramolecule with larger opening or adding a competitive guest.

Graphical abstract: Induced chirality and reversal of phosphomolybdate cluster via modulating its interaction with cyclodextrins

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Publication details

The article was received on 29 Sep 2017, accepted on 13 Dec 2017 and first published on 14 Dec 2017


Article type: Communication
DOI: 10.1039/C7DT03669H
Citation: Dalton Trans., 2018, Advance Article
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    Induced chirality and reversal of phosphomolybdate cluster via modulating its interaction with cyclodextrins

    B. Zhang, W. Guan, F. Yin, J. Wang, B. Li and L. Wu, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C7DT03669H

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