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Issue 8, 2018
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Tunable Prussian blue analogues for the selective synthesis of propargylamines through A3 coupling

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Abstract

M1[Co(CN)6]2/3-type Prussian blue analogues (M1–Co PBAs) were studied as catalysts for the synthesis of propargylamines via A3 coupling of phenylacetylene, benzaldehyde and piperidine. Cu0.86Zn0.14–Co PBA was the best catalyst for the reaction by combining the high conversion obtained with Cu–Co PBA with the excellent selectivity obtained with Zn–Co PBA.

Graphical abstract: Tunable Prussian blue analogues for the selective synthesis of propargylamines through A3 coupling

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Publication details

The article was received on 11 Jan 2018, accepted on 16 Mar 2018 and first published on 04 Apr 2018


Article type: Communication
DOI: 10.1039/C8CY00073E
Citation: Catal. Sci. Technol., 2018,8, 2061-2065
  • Open access: Creative Commons BY-NC license
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    Tunable Prussian blue analogues for the selective synthesis of propargylamines through A3 coupling

    C. Marquez, F. G. Cirujano, C. Van Goethem, I. Vankelecom, D. De Vos and T. De Baerdemaeker, Catal. Sci. Technol., 2018, 8, 2061
    DOI: 10.1039/C8CY00073E

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