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Visible-light-induced photocatalytic benzene/cyclohexane cross-coupling utilizing a ligand-to-metal charge transfer benzene complex adsorbed on titanium oxides

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Abstract

The cross-coupling reaction of benzene and cyclohexane molecules proceeded selectively over Pd-modified titanium dioxide photocatalysts under visible light. A ligand-to-metal charge-transfer (LMCT) complex of benzene adsorbed on titanium oxide was proposed as the key species for the selective formation of the cross-coupling product.

Graphical abstract: Visible-light-induced photocatalytic benzene/cyclohexane cross-coupling utilizing a ligand-to-metal charge transfer benzene complex adsorbed on titanium oxides

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Publication details

The article was received on 19 Dec 2017, accepted on 12 Jan 2018 and first published on 12 Jan 2018


Article type: Communication
DOI: 10.1039/C7CY02566A
Citation: Catal. Sci. Technol., 2018, Advance Article
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    Visible-light-induced photocatalytic benzene/cyclohexane cross-coupling utilizing a ligand-to-metal charge transfer benzene complex adsorbed on titanium oxides

    A. Yamamoto, T. Ohara and H. Yoshida, Catal. Sci. Technol., 2018, Advance Article , DOI: 10.1039/C7CY02566A

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