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Issue 3, 2018
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Distal radical migration strategy: an emerging synthetic means

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Abstract

The remote radical migration strategy has gained considerable momentum. During the past three years, we have witnessed the rapid development of sustainable and practical C–C and C–H bond functionalization by means of long-distance 1,n-radical migration (n = 4, 5, 6) events. Its advent brings our chemical community a new platform to deal with the challenging migration transformations and thus complements the existing ionic-type migration protocols. In this review, the recent achievements in distal radical migration triggered C–C and C–H bond functionalization are summarized.

Graphical abstract: Distal radical migration strategy: an emerging synthetic means

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Publication details

The article was received on 24 Sep 2017 and first published on 27 Nov 2017


Article type: Tutorial Review
DOI: 10.1039/C7CS00507E
Citation: Chem. Soc. Rev., 2018,47, 654-667
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    Distal radical migration strategy: an emerging synthetic means

    W. Li, W. Xu, J. Xie, S. Yu and C. Zhu, Chem. Soc. Rev., 2018, 47, 654
    DOI: 10.1039/C7CS00507E

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