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Reductive Defluorination of Graphite Monofluoride by Weak, Non‐Nucleophilic Reductants Reveals Low‐Lying Electron‐Accepting Sites

Abstract

Graphite monofluoride (GF) can undergo reductive defluorination in the presence of weak, non-nucleophilic reductants. This leads to a new approach to GF-polyaniline composites as cathode materials for significantly improved discharge capacity of primary lithium batteries. We postulate that the reduction is mediated by residual π-bonds in GF.

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Publication details

The article was received on 17 Jan 2018, accepted on 02 May 2018 and first published on 02 May 2018


Article type: Communication
DOI: 10.1039/C8CP00384J
Citation: Phys. Chem. Chem. Phys., 2018, Accepted Manuscript
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    Reductive Defluorination of Graphite Monofluoride by Weak, Non‐Nucleophilic Reductants Reveals Low‐Lying Electron‐Accepting Sites

    Y. Liu, B. W. Noffke, X. Gao, Y. Losovyj, Y. Cui, Y. Fu, K. Raghavachari, A. Siedle and L. Li, Phys. Chem. Chem. Phys., 2018, Accepted Manuscript , DOI: 10.1039/C8CP00384J

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