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Issue 15, 2018
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β-Bi2O3 reduction by laser irradiation in a liquid environment

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Abstract

This study reports the structural and stoichiometric modifications of bismuth oxide nanoparticles in the β phase (β-Bi2O3) by UV pulsed laser irradiation in water or ethanol solutions. Scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, UV-vis diffuse reflectance and high-resolution transmission electron microscopy were used to characterize the synthesized nanomaterials. The various analyses demonstrate that the laser irradiation of β-Bi2O3 nanospheres is a green, fast and effective method to produce Bi2O2CO3 nanosheets or metallic Bi nanoparticles depending on the liquid environment used. Bi subcarbonate is obtained by laser irradiation in water, whereas metallic Bi is produced by laser irradiation in ethanol, and in particular the relative amount of metallic Bi is found to depend on the laser fluence. These typologies of materials find application in several fields, such as photocatalytic processes, light filters and environmental sensors.

Graphical abstract: β-Bi2O3 reduction by laser irradiation in a liquid environment

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Publication details

The article was received on 08 Jan 2018, accepted on 11 Mar 2018 and first published on 13 Mar 2018


Article type: Paper
DOI: 10.1039/C8CP00146D
Citation: Phys. Chem. Chem. Phys., 2018,20, 10292-10301
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    β-Bi2O3 reduction by laser irradiation in a liquid environment

    D. D’Angelo, S. Filice, M. Miritello, C. Bongiorno, E. Fazio, F. Neri, G. Compagnini and S. Scalese, Phys. Chem. Chem. Phys., 2018, 20, 10292
    DOI: 10.1039/C8CP00146D

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