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Assembly of silver-oxo complexes based on N-diphenylphosphanylmethyl-3-aminopyridine and their structures, photocatalysis and photocurrent responses

Abstract

A new P-N hybrid ligand N-diphenylphosphanylmethyl-3-aminopyridine (3-dppmapy) is synthesized and allowed to react with six silver oxysalts including AgTFA (TFA = trifluoroacetic), AgOTF (OTF = trifluoromethanesulfonic), AgNO3, Ag2SO4, AgBz (Bz = benzoate) and AgSal (Sal = salicylate). The reactions result in the formation of two dinuclear complexes [Ag2(Ox)2(3-dppmapy)2] (1, Ox = TFA; 2, Ox = OTF) and four 1D coordination polymers Ag(μ-η2-NO3)(3-dppmapy)•EtOH (3•EtOH), [Ag2(μ-η,η-SO4)(3-dppmapy)2]•CHCl3 (4•CHCl3), [Ag(μ-η2-Bz)(3-dppmapy)] (5) and [Ag(μ-η2-Sal)(3-dppmapy)] (6). All six compounds hold the energy bands among 3.11-3.43 eV in-between the range of simiconductive materials, whereas only 6 possesses good stability in water solution under UV irradiation. In aqueous phase, 6 exhibits high photocatalytic performance in the degradation of eriochrome black T (EBT), amido black (AB) and nigrosine (NO), and also shows relatively prompt anodic photocurrent responses.

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Publication details

The article was received on 03 May 2018, accepted on 12 Jun 2018 and first published on 13 Jun 2018


Article type: Paper
DOI: 10.1039/C8CE00715B
Citation: CrystEngComm, 2018, Accepted Manuscript
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    Assembly of silver-oxo complexes based on N-diphenylphosphanylmethyl-3-aminopyridine and their structures, photocatalysis and photocurrent responses

    L. Xu, W. Yang, C. Liu, Z. Ren and J. Lang, CrystEngComm, 2018, Accepted Manuscript , DOI: 10.1039/C8CE00715B

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