Issue 24, 2018

Ultra-fast precipitation of transient amorphous cerium oxalate in concentrated nitric acid media

Abstract

Amorphous cerium oxalate is characterized and reported here for the first time as a primary nucleating transient precursor for a more stable crystalline hydrated phase, at high supersaturation and in strong acid solutions. Preliminary results point out an initial binodal phase separation leading to precipitation.

Graphical abstract: Ultra-fast precipitation of transient amorphous cerium oxalate in concentrated nitric acid media

Article information

Article type
Communication
Submitted
07 Mar 2018
Accepted
17 May 2018
First published
17 May 2018

CrystEngComm, 2018,20, 3302-3307

Ultra-fast precipitation of transient amorphous cerium oxalate in concentrated nitric acid media

I. Rodríguez-Ruiz, S. Charton, D. Radajewski, T. Bizien and S. Teychené, CrystEngComm, 2018, 20, 3302 DOI: 10.1039/C8CE00358K

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