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Issue 14, 2018
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Silver ethynide clusters constructed with fluorinated β-diketonate ligands

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Abstract

A fluorinated β-diketonate hexafluoroacetylacetone ligand has been employed to construct eight new silver ethynide clusters. Single crystal X-ray analysis revealed that complexes 1–8 are functionalized by hexafluoroacetylacetones as terminal ligands. In compounds 3–8, different kinds of silver ethynide cluster shells enclose various templates, respectively. In 7 and 8, the tert-butylphosphonate ligand functions as a tripodal strut to support the vertex-sharing or fusion of two small silver(I) clusters to form an enlarged composite cluster.

Graphical abstract: Silver ethynide clusters constructed with fluorinated β-diketonate ligands

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Publication details

The article was received on 13 Feb 2018, accepted on 05 Mar 2018 and first published on 05 Mar 2018


Article type: Paper
DOI: 10.1039/C8CE00243F
Citation: CrystEngComm, 2018,20, 2036-2042
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    Silver ethynide clusters constructed with fluorinated β-diketonate ligands

    J. Jin, Y. Shen, Y. Xie and X. Lu, CrystEngComm, 2018, 20, 2036
    DOI: 10.1039/C8CE00243F

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