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Issue 9, 2018
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Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands

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Abstract

Two new coordination networks of formula [Cu(L)2(Cr2O7)], DICRO-L-Cu, (L = 7: 4-(3,5-dimethyl-1H-pyrazol-4-yl)pyridine; 8: 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole) are reported. These compounds represent the first examples of hybrid ultramicroporous materials incorporating pyrazole-based ligands. Ligand length and sterics mitigate against interpenetration between networks, generating internal voids which have been studied in terms of CO2 and N2 sorption.

Graphical abstract: Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands

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Publication details

The article was received on 16 Jan 2018, accepted on 02 Feb 2018 and first published on 12 Feb 2018


Article type: Communication
DOI: 10.1039/C8CE00149A
Citation: CrystEngComm, 2018,20, 1193-1197
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    Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands

    H. S. Scott, S. Mukherjee, D. R. Turner, M. I. J. Polson, M. J. Zaworotko and P. E. Kruger, CrystEngComm, 2018, 20, 1193
    DOI: 10.1039/C8CE00149A

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