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Issue 15, 2018
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Ferroelasticity and piezoelectricity of organic–inorganic hybrid materials with a one-dimensional anionic structure: so similar, yet so different

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Abstract

The synthesis, structural aspects, thermal and dielectric analysis for new members of the ferroic family, polynuclear Bi(III) and Sb(III) halide complexes based on a pyrazolium cation with the formulas (C3N2H5)[BiCl4]·H2O and (C3N2H5)[SbCl4]·H2O, are presented. The former compound was found to undergo a ferroic phase transition of the ferroelastic type at 213/219 K (cooling/heating scans), whereas, the latter one exhibited a piezoelectric feature in the dielectric response function. The molecular motions of pyrazolium cations were analyzed based on the spin–lattice relaxation time of 1H NMR measurements.

Graphical abstract: Ferroelasticity and piezoelectricity of organic–inorganic hybrid materials with a one-dimensional anionic structure: so similar, yet so different

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Publication details

The article was received on 29 Jan 2018, accepted on 02 Mar 2018 and first published on 02 Mar 2018


Article type: Paper
DOI: 10.1039/C8CE00140E
Citation: CrystEngComm, 2018,20, 2112-2119
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    Ferroelasticity and piezoelectricity of organic–inorganic hybrid materials with a one-dimensional anionic structure: so similar, yet so different

    A. Piecha-Bisiorek, K. Mencel, V. Kinzhybalo, A. Szota, R. Jakubas, W. Medycki and W. Zawrocki, CrystEngComm, 2018, 20, 2112
    DOI: 10.1039/C8CE00140E

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