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Issue 13, 2018
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Structural phase diagrams and isomerism inflexible honeycomb-like 2D hydrogen bonded solid solutions

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Abstract

Solid solutions of hydrogen bonded networks of the formula ((1-2H+)3x(2-2H+)3(1–x)([Fe(CN)6]23−))·nH2O, where (1-2H+) and (2-2H+) are bisamidinium H bond donor entities, have been prepared and structurally analysed. The H bonded systems display a honeycomb-like structure, and depending on the x value, three different tilings of the (6,3) system are observed, leading to three different phases. The precise location of the H bond donor cations (2-2H+) has been determined, evidencing H bonding between adjacent cations. The thermal properties of the solid solutions have been studied.

Graphical abstract: Structural phase diagrams and isomerism inflexible honeycomb-like 2D hydrogen bonded solid solutions

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Publication details

The article was received on 05 Jan 2018, accepted on 22 Feb 2018 and first published on 07 Mar 2018


Article type: Paper
DOI: 10.1039/C8CE00023A
Citation: CrystEngComm, 2018,20, 1853-1861
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    Structural phase diagrams and isomerism inflexible honeycomb-like 2D hydrogen bonded solid solutions

    B. Hu, S. Ferlay, N. Gruber-Kyritsakas and M. W. Hosseini, CrystEngComm, 2018, 20, 1853
    DOI: 10.1039/C8CE00023A

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