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Epitaxial growth of the single crystalline films scintillating screens based on the Eu3+ doped RAlO3 (R= Y, Lu, Gd, Tb) perovskites

Abstract

The paper is dedicated to development of scintillating screens for microimaging applications based on the single crystalline films (SCFs) of Eu3+ doped (Y,Lu,Gd,Tb)AlO3 mixed perovskites grown onto YAlO3 substrates using the liquid phase epitaxy (LPE) method with the objective to optimize their X-ray stopping power and light yield. We can confirm that the Eu3+ doped YAlO3 and TbAlO3 SCFs and full set of Lu1−xGdxAlO3 SCFs with x values in x=0−1.0 range can be crystallized on YAlO3 substrates using the LPE technique. The structural quality of films was studied using X-ray diffraction. The optical properties of SCFs of Lu1-xGdxAlO3:Eu (x=0−1) and TbAlO3:Eu mixed perovskites were also studied in this work in comparison with YAlO3:Eu SCF counterpart using the absorption, cathodoluminescence, photoluminescence (PL) emission and excitation spectra and PL decay kinetics as well as light yield measurements under e-beam and α–particles excitation. The Gd3+→Eu3+ and Tb3+→Eu3+ energy transfer processes are observed in Lu1-xGdxAlO3 and TbAlO3:Eu SCFs, respectively, giving reasons to increasing the efficiency of the Eu3+ luminescence in the perovskite hosts. Meanwhile, the highest light yield of the cathodoluminescence (CL) and radio-luminescence (RL) under excitation by α-particles is found only in YAlO3:Eu, Lu0.5Gd0.5AlO3:Eu and GdAlO3:Eu SCFs. The light yield of CL and RL of these SCFs is notably higher than that in TbAlO3:Eu and LuAlO3:Eu SCFs and even slightly (9-11%) overcome the light yield of the conventional Gd3Ga5O12:Eu SCF screens using now in the microimaging detectors.

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Publication details

The article was received on 02 Dec 2017, accepted on 09 Jan 2018 and first published on 10 Jan 2018


Article type: Paper
DOI: 10.1039/C7CE02074K
Citation: CrystEngComm, 2018, Accepted Manuscript
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    Epitaxial growth of the single crystalline films scintillating screens based on the Eu3+ doped RAlO3 (R= Y, Lu, Gd, Tb) perovskites

    Y. Zorenko, V. Gorbenko, T. Zorenko, K. Paprocki, A. Fedorov, F. Riva, P. Douissard, T. Martin, Y. Zhydachevskii and A. Suchocki, CrystEngComm, 2018, Accepted Manuscript , DOI: 10.1039/C7CE02074K

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