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Negative 2D thermal expansion in the halogen bonded acetone bromine complex.

Abstract

The crystal structure of the complex formed between acetone and bromine has been determined between 14K and 200K. The structure exhibits negative 2D thermal expansion at low temperature and colossal thermal expansion in the perpendicular dimension. At low temperature the C=O bond is significantly longer than that observed in free acetone.

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Publication details

The article was received on 06 Nov 2017, accepted on 04 May 2018 and first published on 14 May 2018


Article type: Paper
DOI: 10.1039/C7CE01923H
Citation: CrystEngComm, 2018, Accepted Manuscript
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    Negative 2D thermal expansion in the halogen bonded acetone bromine complex.

    R. H. Jones, K. Knight and W. G. Marshall, CrystEngComm, 2018, Accepted Manuscript , DOI: 10.1039/C7CE01923H

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